Dissemination

Circularly Polarized Luminescence and Photoinduced Spin Polarization in Helicene-Bis-TEMPO Diradicals S. Cadeddu, R. Chowdhury, C. Delpiano Cordeiro, S. Parmar, A. Kramer, M. Cordier, A. Pensel, N. Vanthuyne, R. Sessoli, M. Chiesa, Y.-K. Liao, R. H. Friend, E. Salvadori,* J. Autschbach,* J. Crassous,* https://pubs-acs-org.inc.bib.cnrs.fr/doi/10.1021/jacs.5c04887

“Chiral materials and mechanisms for circularly polarized light-emitting diodes” F. Furlan, J. M. Moreno-Naranjo, N. Gasparini, S. Feldmann, J. Wade, M. J. Fuchter,*

https://www-nature-com.inc.bib.cnrs.fr/articles/s41566-024-01408-z

Photophysical and Chiroptical Properties of Pyrazino-Phenanthroline-Helicene Derivative and its Rhenium(I) Complex” Debsouri Kundu, Dominika Jelonek, Natalia Del Rio, Nicolas Vanthuyne, Monika Srebro-Hooper,* and Jeanne Crassous* https://aces.onlinelibrary.wiley.com/doi/10.1002/asia.202401735

Chirality-Induced Magnetic Polarization by Charge Localization in a Chiral Supramolecular Crystal” Michael Verhage, Pantelis Bampoulis, Marco D. Preuss, Ivo Filot, Rick R. M. Joosten, Heiner Friedrich, E. W. Meijer, and Kees Flipse* https://advanced.onlinelibrary.wiley.com/doi/10.1002/adma.202403807

Decoupling excitons from high-frequency vibrations in organic moleculesPratyush Ghosh, Antonios M. Alvertis, Rituparno Chowdhury, Petri Murto, Alexander J. Gillett, Shengzhi Dong, Alexander J. Sneyd, Hwan-Hee Cho, Emrys W. Evans, Bartomeu Monserrat, Feng Li, Christoph Schnedermann, Hugo Bronstein, Richard H. Friend, Akshay Rao* https://www.nature.com/articles/s41586-024-07246-x

Systematic Investigation of Optical and Chiroptical Properties of Chiral π-Conjugated Oligomers in Solution and Thin Films” Gianluigi Albano,* Andrea Taddeucci, Francesco Zinna, Laura Antonella Aronica, Gennaro Pescitelli, and Lorenzo Di Bari* https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.202400294

Enhancing Circularly Polarized Electroluminescence through Energy Transfer within a Chiral Polymer Host” Juan Manuel Moreno-Naranjo, Francesco Furlan, Jingxiang Wang, Seán Timothy James Ryan, Tomas Matulaitis, Zhiyu Xu, Qianyi Zhang, Louis Minion, Marta Di Girolamo, Tamás Jávorfi, Giuliano Siligardi, Jessica Wade, Nicola Gasparini, Eli Zysman-Colman,* and Matthew John Fuchter* https://advanced.onlinelibrary.wiley.com/doi/full/10.1002/adma.202402194

Triple para-Functionalized Cations and Neutral Radicals of Enantiopure Diaza[4]helicenes” Bibiana Fabri, Tiziana Funaioli, Lucas Frédéric, Christina Elsner, Enrica Bordignon, Francesco Zinna,Lorenzo Di Bari, Gennaro Pescitelli, and Jérôme Lacour* https://pubs.acs.org/doi/10.1021/jacs.3c13487

Stereocontrolled Self-Assembly of a Helicate-Bridged CuI12L4 Cage That Emits Circularly Polarized Light” Huangtianzhi Zhu, Luca Pesce, Rituparno Chowdhury, Weichao Xue, Kai Wu, Tanya K. Ronson, Richard H. Friend,* Giovanni M. Pavan,* and Jonathan R. Nitschke* https://pubs.acs.org/doi/10.1021/jacs.3c11321

Functionalization of Supramolecular Polymers by Dynamic Covalent Boroxine ChemistryM. D. Preuss, T. Schnitzer, S. A. H. Jansen, S. C. J. Meskers, T. H. R. Kuster, X. Lou, E. W. Meijer, G. Vantomme* https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202402644

BINOL blocks as accesible triplet state modulators in BODIPY dyesJ. Jiménez, R. Prieto-Montero, S. Serrano, P. Stachelek, E. Rebollar, B. L. Maroto, F. Moreno, V. Martinez-Martinez, R. Pal, I. García-Moreno*, S. de la Moya* https://pubs-rsc-org.passerelle.univ-rennes1.fr/en/content/articlepdf/2022/cc/d2cc00991a

Hierarchical self-assembly in an RNA-based coordination polymer hydrogelO. El-Zubir, P. Rojas Martinez, G. Dura, C. Doherty, F. Cucinotta, L. E. Mackenzie, R. Pal, B. R. Horrocks, A. Houlton* https://pubs.rsc.org/en/content/articlepdf/2023/dt/d3dt00634d

Circularly polarised luminescence in an RNA-based homochiral, self-reparing, coordination polymer hydrogelO. El-Zubir, P. Rojas Martinez, G. Dura, L. L. G. Al-Mahamad, T. Pope, T. J. Penfold, L. E. Mackenzie, R. Pal, J. Mosely, F. Cucinotta, L. F. McGarry, B. R. Horrocks, A. Houlton* https://pubs.rsc.org/en/content/articlepdf/2022/tc/d2tc00366j

Rational Design of New Conjugated Polymers with Main Chain Chirality for Efficient Optoelectronic Devices: Carbo[6]Helicene and Indacenodithiophene Copolymers as Model CompoundsC. Gedeon, N. Del Rio, F. Furlan, A. Taddeucci, N. Vanthuyne, V. G. Gregoriou, M. J. Fuchter, G. Siligardi, N. Gasparini, J. Crassous,* C. L. Chochos* https://onlinelibrary.wiley.com/doi/epdf/10.1002/adma.202314337

Synthesis and Structural Diversification of Circularly Polarised Luminescence Active, Helically Chiral, “Confused” N,N,O,C-BODIPY R. G. Clarke, J. Weatherston, R. A. Taj-Aldeen, P. G. Waddell, W. McFarlane, T. J. Penfold, J. Bogaerts, W. Herrebout, L. E. Mackenzie, R. Pal, M. J. Hall* https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/cptc.202200194

Stereocontrolled Self-Assembly of a Helicate-Bridged CuI12L4 Cage That Emits Circularly Polarized LightH. Zhu, L. Pesce, R. Chowdhury, W. Xue, K. Wu, T. K. Ronson, R. H. Friend* G. M. Pavan*, J. R. Nitschke* https://pubs.acs.org/doi/epdf/10.1021/jacs.3c11321

Ligand Chirality Transfer from Solution State to the Crystalline Self-Assemblies in Circularly Polarized Luminescence (CPL) Active Lanthanide SystemsD. F. Caffrey, T. Gorai, B. Rawson, M. Martínez-Calvo, J. A. Kitchen, N. S. Murray, O. Kotova*, Steve Comby, R. D. Peacock, P. Stachelek, R. Pal*, T. Gunnlaugsson* https://onlinelibrary.wiley.com/doi/epdf/10.1002/advs.202307448

Engineering Soluble Diketopyrrolopyrrole Chromophore Stacks from a Series of Pd(II)-Based RavelsI. Regeni, R. Chowdhury, K. Terlinden, S. Horiuchi, J. J. Holstein, S. Feldmann, G. H. Clever* https://onlinelibrary.wiley.com/doi/10.1002/anie.202308288

Unlocking same-sign CPL: solvent effects on spectral form and racemisation kinetics in nine-coordinate chiral europium(III) complexesD. F. de Rosa, M. Starck, D. Parker, R. Pal*     https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202303227

Fast Near-Infrared Photodetectors Based on Nontoxic and Solution-Processable AgBiS2Y-T. Huang, D. Nodari, F. Furlan, Y. Zhang, M. Rusu, L. Dai, Z. Andaji-Garmaroudi, D. Darvill, X. Guo, M. Rimmele, T. Unold, M. Heeney, S. D. Stranks, H. Sirrighaus, A. Rao, N. Gasparini*, L. R. Z. Hoye* https://onlinelibrary.wiley.com/doi/epdf/10.1002/smll.202310199

Two-Photon Circularly Polarized Luminescence of Chiral Eu Complexes O. G. Willis, F. Petri, D. F. De Rosa, A. Mandoli, R. Pal*, F. Zinna*, L. Di Bari* https://pubs.acs.org/doi/10.1021/jacs.3c05957

Porphyrin- and Bodipy-helicene conjugates: syntheses, separation of enantiomers and chiroptical properties V. Silber, M. Jean, N. Vanthuyne, N. del Rio, P. Matozzo, J. Crassous*, R. Ruppert* https://pubs.rsc.org/en/content/articlepdf/2023/ob/d3ob01459b

Spatially Resolved Chiroptical Spectroscopies Emphasizing Recent Applications to Thin Films of Chiral Organic Dyes G. Albano, A. Taddeucci, G. Pescitelli, L. Di Bari* https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/chem.202301982

Weakly Self-Assembled [6]Helicenes: Circularly Polarized Light and Spin Filtering Properties R. Rodriguez, C. Naranjo, A. Kumar, K. Dhbaibi, P. Matozzo, F. Camerel, N. Vanthuyne, R. Gomez, R. Naaman*, L. Sanchez*, J. Crassous* https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/chem.202302254

Tuning Halide Composition Allows Low Dark Current Perovskite Photodetectors With High Specific Detectivity F. Furlan, D. Nodari, E. Palladino, E. Angela, L. Mohan, J. Briscoe, M. J. Fuchter, T. J. Macdonald, G. Grancini, M. A. McLachlan, N. Gasparini* https://onlinelibrary.wiley.com/doi/full/10.1002/adom.202201816

Mesitylated trityl radicals, a platform for doublet emission: symmetry breaking, charge-transfer states and conjugated polymers P. Murto, R. Chowdhury, S. Gorgon, E. Guo, W. Zeng, B. Li, Y. Sun, H. Francis, R. H. Friend*, H. Bronstein* https://www.nature.com/articles/s41467-023-39834-2

Insights into the origins of inverted circular dichroism in thin films of a chiral side chain polyfluorene L. Minion*, J. Wade, J. M. Moreno-Naranjo, S. Ryan, G. Siligardi, M. J. Fuchter* https://onlinelibrary.wiley.com/doi/full/10.1002/chir.23601

Circularly Polarized Microscopy of Thin Films of Chiral Organic Dyes A. Taddeucci, F. Zinna, G. Siligardi, L. Di Bari* https://pubs.acs.org/doi/10.1021/cbmi.3c00049

Circularly Polarized Luminescence from New Heteroleptic Eu(III) and Tb(III) Complexes S. Ruggieri, S. Mizzoni, C. Nardon, E. Cavalli, C. Sissa, M. Anselmi, P. G. Cozzi, A. Gualandi, M. Sanadar, A. Melchior*, F. Zinna, O. G. Willis, L. Di Bari*, F. Piccinelli* https://pubs.acs.org/doi/full/10.1021/acs.inorgchem.3c00196

Chiral Diketopyrrolo[3,4-c]pyrrole-1,2,3-1H-triazole Dyes with Highly Tuneable Properties in Solution and Thin Films G. Albano, F. Zinna, A. Taddeucci, M. A. M. Capozzi, G. Pescitelli, A. Punzi*, L. Di Bari*, G. M. Farinola https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/chem.202300291

Enantiopure cycloplatinated pentahelicenic N-heterocyclic carbenic complexes that display long-lived circularly polarized phosphorescence D. Kundu, N. del Rio, M. Cordier, N. Vanthuyne, E. V. Victoria Puttock, S. C. J. Meskers, J. A. Garreth Williams*, M. Srebro-Hooper*, J. Crassous* https://pubs.rsc.org/en/content/articlelanding/2023/dt/d3dt00577a

Materials for chiral light control J. Crassous, M. J. Fuchter, D. E. Freedman, N. A. Kotov, J. Moon, M. C. Beard, S. Feldmann https://www.nature.com/articles/s41578-023-00543-3

NIR-CPL from chiral complexes of lanthanides and d-metals O. G. Willis, F. Zinna, L. di Bari* https://onlinelibrary.wiley.com/doi/10.1002/anie.202302358

Rapid handheld time-resolved circularly polarised luminescence photography camera for life and material sciences D. F. de Rosa, P. Stachelek, D. J. Black, R. Pal* https://www.nature.com/articles/s41467-023-37329-8.pdf

“Intense 1400-1600 nm circularly polarised luminescence from homo- and heteroleptic chiral erbium complexes O. G. Willis, A. Pucci, E. Cavalli, F. Zinna*, L. di Bari* https://pubs.rsc.org/en/content/articlelanding/2023/tc/d3tc00034f

Synthesis, structural characterization, and chiroptical properties of planarly and axially chiral boranils A. Mace, K. Hamrouni, P. Matozzo, M. Coehlo, J. Firlej, F. Aloui, N. Vanthuyne, E. Caytan, M. Cordier, G. Pieters, M. Srebro-Hooper*, F. Berree*, B. Carboni, J. Crassous* https://onlinelibrary.wiley.com/doi/10.1002/chir.23537

Circularly polarized luminescence from Tb(III) interacting with chiral polyether macrocycles A. Homberg, F. Navazio, A. Le Tellier, F. Zinna, A. Furstenberg, C. Besnard, L. di Bari, J. Lacour* https://pubs.rsc.org/en/Content/ArticleLanding/2022/DT/D2DT02627A

How Subtle Changes Can Make a Difference Reproducibility in Complex Supramolecular Systems T. Schnitzer, M. D. Preuss, J. van Basten, S. M. C. Schoenmakers, A. J. H. Spiering, G. Vantomme, E. W. Meijer* https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202206738

Chemo- and Regioselective Multiple C(sp2)-H Insertions of Malonate Metal Carbenes for Late-Stage Functionalizations of Azahelicenes Y. Nikolova, B. Fabri, P. Moneva Lorente, A. Guarnieri-Ibañez, A. de Aguirre, Y. Soda, G. Pescitelli, F. Zinna, C. Besnard, L. Guénée, D. Moreau, L. di Bari, E. Bakker, A. I. Poblador-Bahamonde, J. Lacour* https://onlinelibrary.wiley.com/doi/epdf/10.1002/anie.202210798

Triple Regioselective Functionalization of Cationic [4]Helicenes via Iridium-Catalyzed Borylation and Suzuki Cross-Coupling Reactivity L. Frédéric, B. Fabri, L. Guénée, F. Zinna, L. di Bari, J. Lacour* https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202201853

Efficient 1400-1600 nm Circularly Polarized Luminescence from a Tuned Chiral Erbium Complex O. G. Willis, F. Petri, G. Pescitelli, A. Pucci, E. Cavalli, A. Mandoli, F. Zinna*, L. di Bari* https://onlinelibrary.wiley.com/doi/epdf/10.1002/anie.202208326

Mutual Monomer Orientation to Bias the Supramolecular Polymerization of [6]Helicenes and the Resulting Circularly Polarized Light and Spin Filtering Properties R. Rodriguez, C. Naranjo, A. Kumar, P. Matozzo, T. Kumar Das, Q. Zhu, N. Vanthuyne, R. Gomez, R. Naaman*, L. Sanchez*, J. Crassous* https://pubs.acs.org/doi/10.1021/jacs.2c00556

Circularly polarized luminescence laser scanning confocal microscopy to study live cell chiral molecular interactions P. Stachelek, L. MacKenzie, D. Parker, R. Pal* https://www.nature.com/articles/s41467-022-28220-z.pdf

Remarkable near-infrared chiroptical properties of chiral Yb, Tm and Er complexes O. G. Willis, F. Zinna*, G. Pescitelli, C. Micheletti, L. di Bari* https://pubs.rsc.org/en/content/articlelanding/2022/DT/D1DT03843E

Versatile Para-Substituted Pyridine Lanthanide Coordination Complexes Allow Late Stage Tailoring of Complex Function M. Starck,* J. D. Fradgley, D. F. De Rosa, A. S. Batsanov, M. Papa, M. J. Taylor, J. E. Lovett, J. C. Lutter, M. J. Allen, D. Parker* https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/chem.202103243

Pasteur and chirality: A story of how serendipity favors the prepared minds 🌀 G. Vantomme, J. Crassous https://onlinelibrary.wiley.com/doi/full/10.1002/chir.23349

An S-Shaped Double Helicene Showing both Multi-Resonance Thermally Activated Delayed Fluorescence and Circularly Polarized Luminescence J. Marques dos Santos, D. Sun, J. M Moreno Naranjo, D. Hall, F. Zinna, S. T. J. Ryan, W. Shi, T. Matulaitis, D. B. Cordes, A. M. Z. Slawin, D. Beljonne, S. L. Warriner, Y. Olivier*, M. J. Fuchter*, E Zysman-Colman* https://pubs.rsc.org/en/content/articlepdf/2022/tc/d2tc00198e

Chirality and Supramolecular Copolymerizations – The Elusive Role of Subtle Solvation Effects” M. D. Preuss, S. A. H. Jansen, G. Vantomme, E. W. Meijer* https://onlinelibrary.wiley.com/doi/epdf/10.1002/ijch.202100078

Exciton coupling chirality in helicene-porphyrin conjugates 🌀 K. Dhbaibi, P. Matozzo, L. Abella, M. Jean, N. Vanthuyne, J. Autschbach*, L. Favereau*, J. Crassous* https://pubs.rsc.org/en/content/articlepdf/2021/cc/d1cc03314j

Spin Filtering in Supramolecular Polymers Assembled from Achiral Monomers Mediated by Chiral Solvents A. K. Mondal, M. D. Preuss, M. L. Ślęczkowski, T. K. Das, G. Vantomme, E. W. Meijer*, R. Naaman* https://pubs.acs.org/doi/10.1021/jacs.1c02983

Dinuclear Rhenium Complexes with a Bridging Helicenebis-bipyridine Ligand: Synthesis, Structure, and Photophysical and Chiroptical Properties🌀 N. Saleh, D. Kundu, N. Vanthuyne, J. Olesiak-Banska, A. Pniakowska, K. Matczyszyn, V. Y. Chang, G. Muller, J. A. G. Williams, M. Srebro-Hooper*, J. Autschbach, J. Crassous* https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/cplu.202000559